The synthesis and characterization of pyridine cored dentrimeric s-Triazine Schiff bases: Investigation of their [MSalen/Salophen] (M = Cr3+, Fe3+, Co3+ and Zr4+) capped complexes

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dc.authoridUYSAL, Saban/0000-0003-1061-6143
dc.contributor.authorKiymaz, Kubra
dc.contributor.authorUysal, Saban
dc.date.accessioned2024-09-29T16:00:26Z
dc.date.available2024-09-29T16:00:26Z
dc.date.issued2023
dc.departmentKarabük Üniversitesien_US
dc.description.abstractIn this study, 2,6-bis(4,6-dichloro-1,3,5-triazine-2-yl-amino)pyridine (III) was obtained by reacting cyanuric chloride with 2,6-diaminopyridine at 0 ?. Then, 2,6-bis(4,6-(4-formyphenoxy)-1,3,5-triazine-2-yl-amino)pyridine (IV) was obtained by reacting the compounds with 4-hydroxybenzaldehyde. The first tar-get ligand 2,6-bis(4,6-(4-(4-carboxybenzylimino) phenoxy)-1,3,5-triazine-2-yl amino) pyridine (V) and second target ligand 2,6-bis(4,6-(4-(3,5-dicarboxybenzylimino)phenoxy)-1,3,5-triazine-2-yl-amino) pyridine (VI) were obtained by reacting compound IV with 4-aminobenzoic acid or 5-aminoisophtalic acid, respectively. [MSalen/Saloph] capped complexes were obtained from the reaction of V and VI codded ligands and the [(MSalen/Saloph)(2)O] (M = Cr3+, Fe3+, Co3+ and Zr4+) starting complexes in 1,4-dioxane or DMF media, respectively. The ligands were characterized by using 1H-NMR, FT-IR spectroscopy, ESI-MS and elemental analysis techniques. The complexes were characterized by using FT-IR, MALDI-TOF spectrometer, UV-Vis spectroscopies, elemental analysis, magnetic susceptibility, and TGA-DTA techniques. Metal contents of the complexes were determined by using ICP-AES spectroscopy. (C) 2022 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipKarabuk University Scientific Research Projects Coordinatorship [FYL-2020-2339]en_US
dc.description.sponsorshipWe acknowledge that this study was financially supported by the Karabuk University Scientific Research Projects Coordinatorship (Project No: FYL-2020-2339) .en_US
dc.identifier.doi10.1016/j.molstruc.2022.134029
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85137039294en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2022.134029
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5139
dc.identifier.volume1271en_US
dc.identifier.wosWOS:000859282600009en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCyanuric chlorideen_US
dc.subjects-Triazineen_US
dc.subjectSalenen_US
dc.subjectSalophen_US
dc.subjectDentrimeric complexesen_US
dc.titleThe synthesis and characterization of pyridine cored dentrimeric s-Triazine Schiff bases: Investigation of their [MSalen/Salophen] (M = Cr3+, Fe3+, Co3+ and Zr4+) capped complexesen_US
dc.typeArticleen_US

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