Diaquabis(2-bromobenzoato-?O)bis(nicotinamide-?N1)zinc(II)

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dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.authoridOzturkkan, Fureya Elif/0000-0001-6376-4161
dc.contributor.authorHokelek, Tuncer
dc.contributor.authorDal, Hakan
dc.contributor.authorTercan, Baris
dc.contributor.authorOzbek, F. Elif
dc.contributor.authorNecefoglu, Hacali
dc.date.accessioned2024-09-29T16:03:14Z
dc.date.available2024-09-29T16:03:14Z
dc.date.issued2009
dc.departmentKarabük Üniversitesien_US
dc.description.abstractThe title Zn-II complex, [Zn(C7H4BrO2)(2)(C6H6N2O)(2)(H2O)(2)], is centrosymmetric with the Zn atom on an inversion center. The molecule contains two 2-bromobenzoate (BB) and two nicotinamide (NA) ligands and two coordinated water molecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Zn atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 31.14 (12)degrees, while the pyridine and benzene rings are oriented at a dihedral angle of 83.54 (5)degrees. In the crystal structure, O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds link the molecules into infinite chains. A weak C-H center dot center dot center dot pi interaction is also present.en_US
dc.identifier.doi10.1107/S1600536809015645
dc.identifier.endpageU1270en_US
dc.identifier.issn2056-9890
dc.identifier.pmid21583825en_US
dc.identifier.scopus2-s2.0-66749165374en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageM607en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536809015645
dc.identifier.urihttps://hdl.handle.net/20.500.14619/5972
dc.identifier.volume65en_US
dc.identifier.wosWOS:000265702000103en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectMolecular-Structureen_US
dc.subjectCrystalen_US
dc.titleDiaquabis(2-bromobenzoato-?O)bis(nicotinamide-?N1)zinc(II)en_US
dc.typeArticleen_US

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