Diaquabis(N,N'-diethylnicotinamide-?N 1)bis(4-ethylbenzoato-?O)copper(II)
Küçük Resim Yok
Tarih
2011
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Wiley-Blackwell
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
The title CuII complex, [Cu(C9H9O2)(2)(C10H14N2O)(2)(H2O)(2)], contains two 4-ethylbenzoate (PEB) ligands, two monodentate diethylnicotinamide (DENA) ligands and two water molecules. The four O atoms in the equatorial plane around the CuII ion form a slightly distorted square-planar arrangement, while the distorted octahedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. Intramolecular O-H...O hydrogen bonds link the water molecules to the carboxylate groups. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 4.6 (3) and 3.7 (2)degrees, while the pyridine rings and the benzene rings are oriented at dihedral angles of 6.82 (11) and 3.63 (14)degrees. In the crystal, intermolecular O-H...O hydrogen bonds link the molecules into chains propagating along [010]. C-H...O interactions and a pi-pi contact between the pyridine rings [centroid-centroid distance = 3.469 (2) A] are also observed.
Açıklama
Anahtar Kelimeler
Kaynak
Acta Crystallographica Section E-Structure Reports Online
WoS Q Değeri
Q4
Scopus Q Değeri
N/A
Cilt
67
