Diaquabis(N,N'-diethylnicotinamide-?N 1)bis(4-ethylbenzoato-?O)copper(II)
dc.authorid | Hokelek, Tuncer/0000-0002-8602-4382 | |
dc.authorid | AKTAS, Vedat/0000-0003-3413-5424 | |
dc.contributor.author | Necefoglu, Hacali | |
dc.contributor.author | Maraci, Ali | |
dc.contributor.author | Aktas, Vedat | |
dc.contributor.author | Tercan, Baris | |
dc.contributor.author | Hokelek, Tuncer | |
dc.date.accessioned | 2024-09-29T16:03:22Z | |
dc.date.available | 2024-09-29T16:03:22Z | |
dc.date.issued | 2011 | |
dc.department | Karabük Üniversitesi | en_US |
dc.description.abstract | The title CuII complex, [Cu(C9H9O2)(2)(C10H14N2O)(2)(H2O)(2)], contains two 4-ethylbenzoate (PEB) ligands, two monodentate diethylnicotinamide (DENA) ligands and two water molecules. The four O atoms in the equatorial plane around the CuII ion form a slightly distorted square-planar arrangement, while the distorted octahedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. Intramolecular O-H...O hydrogen bonds link the water molecules to the carboxylate groups. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 4.6 (3) and 3.7 (2)degrees, while the pyridine rings and the benzene rings are oriented at dihedral angles of 6.82 (11) and 3.63 (14)degrees. In the crystal, intermolecular O-H...O hydrogen bonds link the molecules into chains propagating along [010]. C-H...O interactions and a pi-pi contact between the pyridine rings [centroid-centroid distance = 3.469 (2) A] are also observed. | en_US |
dc.description.sponsorship | Scientific and Technological Research Council of Turkey [108 T657] | en_US |
dc.description.sponsorship | The authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskisehir, Turkey, for the use of X-ray diffractometer. This work was supported financially by the Scientific and Technological Research Council of Turkey (grant No. 108 T657). | en_US |
dc.identifier.doi | 10.1107/S1600536811018666 | |
dc.identifier.endpage | U1297 | en_US |
dc.identifier.issn | 1600-5368 | |
dc.identifier.pmid | 21754663 | en_US |
dc.identifier.scopus | 2-s2.0-79957979054 | en_US |
dc.identifier.scopusquality | N/A | en_US |
dc.identifier.startpage | M780 | en_US |
dc.identifier.uri | https://doi.org/10.1107/S1600536811018666 | |
dc.identifier.uri | https://hdl.handle.net/20.500.14619/6031 | |
dc.identifier.volume | 67 | en_US |
dc.identifier.wos | WOS:000291215800099 | en_US |
dc.identifier.wosquality | Q4 | en_US |
dc.indekslendigikaynak | Web of Science | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.indekslendigikaynak | PubMed | en_US |
dc.language.iso | en | en_US |
dc.publisher | Wiley-Blackwell | en_US |
dc.relation.ispartof | Acta Crystallographica Section E-Structure Reports Online | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.title | Diaquabis(N,N'-diethylnicotinamide-?N 1)bis(4-ethylbenzoato-?O)copper(II) | en_US |
dc.type | Article | en_US |