Diaquabis(N,N'-diethylnicotinamide-?N 1)bis(4-ethylbenzoato-?O)copper(II)

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dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.authoridAKTAS, Vedat/0000-0003-3413-5424
dc.contributor.authorNecefoglu, Hacali
dc.contributor.authorMaraci, Ali
dc.contributor.authorAktas, Vedat
dc.contributor.authorTercan, Baris
dc.contributor.authorHokelek, Tuncer
dc.date.accessioned2024-09-29T16:03:22Z
dc.date.available2024-09-29T16:03:22Z
dc.date.issued2011
dc.departmentKarabük Üniversitesien_US
dc.description.abstractThe title CuII complex, [Cu(C9H9O2)(2)(C10H14N2O)(2)(H2O)(2)], contains two 4-ethylbenzoate (PEB) ligands, two monodentate diethylnicotinamide (DENA) ligands and two water molecules. The four O atoms in the equatorial plane around the CuII ion form a slightly distorted square-planar arrangement, while the distorted octahedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. Intramolecular O-H...O hydrogen bonds link the water molecules to the carboxylate groups. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 4.6 (3) and 3.7 (2)degrees, while the pyridine rings and the benzene rings are oriented at dihedral angles of 6.82 (11) and 3.63 (14)degrees. In the crystal, intermolecular O-H...O hydrogen bonds link the molecules into chains propagating along [010]. C-H...O interactions and a pi-pi contact between the pyridine rings [centroid-centroid distance = 3.469 (2) A] are also observed.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey [108 T657]en_US
dc.description.sponsorshipThe authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskisehir, Turkey, for the use of X-ray diffractometer. This work was supported financially by the Scientific and Technological Research Council of Turkey (grant No. 108 T657).en_US
dc.identifier.doi10.1107/S1600536811018666
dc.identifier.endpageU1297en_US
dc.identifier.issn1600-5368
dc.identifier.pmid21754663en_US
dc.identifier.scopus2-s2.0-79957979054en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpageM780en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536811018666
dc.identifier.urihttps://hdl.handle.net/20.500.14619/6031
dc.identifier.volume67en_US
dc.identifier.wosWOS:000291215800099en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherWiley-Blackwellen_US
dc.relation.ispartofActa Crystallographica Section E-Structure Reports Onlineen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleDiaquabis(N,N'-diethylnicotinamide-?N 1)bis(4-ethylbenzoato-?O)copper(II)en_US
dc.typeArticleen_US

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